2nd generation Biodiesel

topic posted Fri, August 4, 2006 - 9:06 AM by  Materpiscis
NExBTL diesel, in contrast to rapeseed methyl ester, is a clear and colorless paraffin, and contains no oxygen. It is used to improve the quality of petro-diesel; its' quality is higher since it has a homogenous source, namely plant-synthesized fatty acids. It doesn't require any special engine repairs and it doesn't foul systems like ester biodiesel. It is produced by direct hydrogenation of the plant oil (chemically, triglyceride) into alkane, water and carbon oxides on a nickel-molybdenum catalyst. The total CO2 produced in the entire lifecycle is only 0.45 to 1.33 kg CO2/kg oil, in contrast to transesterified fuel with 1.4-2.0 kg CO2/kg oil, or mineral diesel with 3.4 kg CO2/kg oil. [www.termo.hut.fi/Ene-39/006/biodiesel1.ppt] Therefore, it's not only an "oil derivative" like ester.
posted by:
Materpiscis
SF Bay Area
  • Re: 2nd generation Biodiesel

    Tue, January 15, 2008 - 5:05 PM
    I have an older diesel... how does this biodiesel affect the natural rubber in older engines?
    • Re: 2nd generation Biodiesel

      Thu, January 17, 2008 - 9:14 PM
      If indeed it's feedstock is plant-derived fatty acids, it would have similar if not identical lubricity and solvent properties as today's bio. Namely, replace any butyl rubber lines with Viton. Replace fuel filter as req'd. Done.
      • Re: 2nd generation Biodiesel

        Tue, January 29, 2008 - 3:12 PM
        If the triglycerides are completely hydrogenated down to alkanes the solvent and lubricity properties would be completely different than biodiesel. The alkanes would have a lower molecular weight and reduced polarity compared to the corresponding esters. This should lead to a thinner, more volatile fuel with reduced solvent properties.
        • Re: 2nd generation Biodiesel

          Tue, January 29, 2008 - 3:17 PM
          I couldn't find details on the process at the link given above. If it is like most other "complete" hydrogenations (all the way to alkanes), extreme pressure and often high temperatures would be required necessitating special thick walled pressure reactors. Would love more details

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